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The earliest evidence of glazed brick is the discovery of glazed bricks in the Elamite Temple at Chogha Zanbil, dated to the 13th century BC. Glazed and colored bricks were used to make low reliefs in Ancient Mesopotamia, most famously the Ishtar Gate of Babylon (c. 575 BC), now partly reconstructed in Berlin, with sections elsewhere. Mesopotamian craftsmen were imported for the palaces of the Persian Empire such as Persepolis.

Human beings appear to have been making their own ceramics for at least 26,000 years, subjecting clay and silica to intense heat to fuse and form ceramic materials. The earliest found so far were in southern central Europe and were sculpted figures, not dishes. The earliest known pottery was made by mixing animal products with clay and firing it at up to 800 °C (1,500 °F). While pottery fragments have been found up to 19,000 years old, it was not until about 10,000 years later that regular pottery became common. An early people that spread across much of Europe is named after its use of pottery: the Corded Ware culture. These early Indo-European peoples decorated their pottery by wrapping it with rope while it was still wet. When the ceramics were fired, the rope burned off but left a decorative pattern of complex grooves on the surface.

Reinforcing bars in masonry construction have been used since antiquity, with Rome using iron or wooden rods in arch construction. Iron tie rods and anchor plates were later employed across Medieval Europe, as a device to reinforce arches, vaults, and cupolas. 2,500 meters of rebar was used in the 14th-century Château de Vincennes.

During the 18th century, rebar was used to form the carcass of the Leaning Tower of Nevyansk in Russia, built on the orders of the industrialist Akinfiy Demidov. The wrought iron used for the rebar was of high quality, and there is no corrosion on the bars to this day. The carcass of the tower was connected to its cast iron tented roof, crowned with one of the first known lightning rods.

However, not until the mid-19th century, with the embedding of steel bars into concrete (thus producing modern reinforced concrete), did rebar display its greatest strengths. Several people in Europe and North America developed reinforced concrete in the 1850s. These include Joseph-Louis Lambot of France, who built reinforced concrete boats in Paris (1854) and Thaddeus